Publications

2018

Cold ion spectroscopy for structural identifications of biomolecules

O. Boyarkine

International Reviews in Physical Chemistry. 2018-12-07.

DOI : 10.1080/0144235X.2018.1547453.

Intrinsic structure of pentapeptide Leu-enkephalin: geometry optimization and validation by comparison of VSCF-PT2 calculations with cold ion spectroscopy

Tapta Kanchan Roy; V. Kopysov; A. Pereverzev; J. Šebek; R. B. Gerber et al.

Phys. Chem. Chem. Phys.. 2018-09-07.

DOI : 10.1039/C8CP03989E.

Peptide Bond Ultraviolet Absorption Enables Vibrational Cold-Ion Spectroscopy of Nonaromatic Peptides

A. Y. Pereverzev; V. N. Kopysov; O. V. Boyarkin

The Journal of Physical Chemistry Letters. 2018-08-29.

DOI : 10.1021/acs.jpclett.8b02148.

Identification of isoforms of aspartic acid residues in peptides by 2D UV-MS fingerprinting of cold ions

V. Kopysov; M. V. Gorshkov; O. V. Boyarkin

The Analyst. 2018-07-06.

DOI : 10.1039/C7AN02044A.

Initial Steps of Amyloidogenic Peptide Assembly Revealed by Cold-Ion Spectroscopy

J. Ujma; V. Kopysov; N. S. Nagornova; L. G. Migas; M. G. Lizio et al.

Angewandte Chemie-International Edition. 2018.

DOI : 10.1002/anie.201710188.

2017

High Susceptibility of Histidine to Charge Solvation Revealed by Cold Ion Spectroscopy

A. Y. Pereverzev; V. Kopysov; O. V. Boyarkin

Angewandte Chemie-International Edition. 2017.

DOI : 10.1002/anie.201709437.

A Decapeptide Hydrated by Two Waters: Conformers Determined by Theory and Validated by Cold Ion Spectroscopy

T. K. Roy; N. S. Nagornova; O. V. Boyarkin; R. B. Gerber

Journal Of Physical Chemistry A. 2017.

DOI : 10.1021/acs.jpca.7b10357.

Multilaser Conformer-Selective Spectroscopy of Cold Biomolecular Ions in the Gas Phase

A. Pereverzev / O. Boyarkine (Dir.)

Lausanne, EPFL, 2017.

DOI : 10.5075/epfl-thesis-8012.

Exploring the relevance of gas-phase structures to biology: cold ion spectroscopy of the decapeptide neurokinin A

A. Pereverzev; O. V. Boyarkin

Physical Chemistry Chemical Physics -Cambridge- Royal Society of Chemistry. 2017.

DOI : 10.1039/c6cp07953a.

Identification of Isomeric Ephedrines by Cold Ion UV Spectroscopy: Toward Practical Implementation

V. Kopysov; A. Makarov; O. V. Boyarkin

Analytical Chemistry. 2017.

DOI : 10.1021/acs.analchem.6b04182.

On the functional group composition of organic aerosol

G. Ruggeri / S. Takahama (Dir.)

Lausanne, EPFL, 2017.

DOI : 10.5075/epfl-thesis-7578.

2016

Method and apparatus for the analysis of molecules using mass spectrometry and optical spectroscopy

A. Makarov; O. Boyarkine; V. Kopysov

2016.

Patent number(s) :
US2017243728
EP3207556
WO2016059037
GB2531336

Novel Approaches in Cold Ion Spectroscopy for Structural Characterization of Biomolecules in the Gas Phase

V. Kopysov / O. Boyarkine (Dir.)

Lausanne, EPFL, 2016.

DOI : 10.5075/epfl-thesis-7117.

Vibrational Signatures of Conformer-Specific Intramolecular Interactions in Protonated Tryptophan

A. Pereverzev; X. Cheng; N. Nagornova; D. Reese; R. Steele et al.

Journal of Physical Chemistry A. 2016.

DOI : 10.1021/acs.jpca.6b05605.

Nonstatistical UV Fragmentation of Gas-Phase Peptides Reveals Conformers and Their Structural Features

V. Kopysov; A. Makarov; O. V. Boyarkin

Journal of physical chemistry letters. 2016.

DOI : 10.1021/acs.jpclett.6b00292.

Resonance Energy Transfer Relates the Gas-Phase Structure and Pharmacological Activity of Opioid Peptides

V. Kopysov; O. Boyarkin

Angewandte Chemie -International Edition in English-. 2016.

DOI : 10.1002/anie.201508915.

2015

Colors for Molecular Masses: Fusion of Spectroscopy and Mass Spectrometry for Identification of Biomolecules

V. Kopysov; A. Makarov; O. Boyarkine

Analytical Chemistry. 2015.

DOI : 10.1021/acs.analchem.5b00822.

Dissociation threshold of H218O: Validating ab initio calculations by state-selective triple-resonance spectroscopy

D. S. Makarov; M. A. Koshelev; N. F. Zobov; O. V. Boyarkin

Chemical Physics Letters. 2015.

DOI : 10.1016/j.cplett.2015.03.036.

Conformational Structures of a Decapeptide Validated by First Principles Calculations and Cold Ion Spectroscopy

T. K. Roy; V. Kopysov; N. S. Nagornova; T. R. Rizzo; O. V. Boyarkin et al.

Chemphyschem. 2015.

DOI : 10.1002/cphc.201500085.

Cryogenic Methods for the Spectroscopy of Large, Biomolecular Ions

T. R. Rizzo; O. V. Boyarkin

Gas-phase IR Spectroscopy for the Structural Characterization of Biomolecules; Berlin: Springer, 2015. p. 43-97.

2014

Fragmentation mechanism of UV-excited peptides in the gas phase

A. Zabuga; M. Z. Kamrath; O. V. Boyarkin; T. R. Rizzo

Journal of Chemical Physics. 2014.

DOI : 10.1063/1.4897158.

Identification of Tyrosine-Phosphorylated Peptides Using Cold Ion Spectroscopy

V. Kopysov; N. S. Nagornova; O. V. Boyarkin

Journal of the American Chemical Society. 2014.

DOI : 10.1021/ja5053544.

Cryogenically cooled octupole ion trap for spectroscopy of biomolecular ions

O. V. Boyarkin; V. Kopysov

Review of Scientific Instruments. 2014.

DOI : 10.1063/1.4868178.

Microhydration Effects on the Encapsulation of Potassium Ion by Dibenzo-18-Crown-6

Y. Inokuchi; T. Ebata; T. R. Rizzo; O. V. Boyarkin

Journal Of The American Chemical Society. 2014.

DOI : 10.1021/ja4086066.

2013

Exploring the Mechanism of IR–UV Double-Resonance for Quantitative Spectroscopy of Protonated Polypeptides and Proteins

N. S. Nagornova; T. R. Rizzo; O. V. Boyarkin

Angewandte Chemie -International Edition. 2013.

DOI : 10.1002/anie.201301656.

Accurate bond dissociation energy of water determined by triple-resonance vibrational spectroscopy and ab initio calculations

O. V. Boyarkin; M. A. Koshelev; O. Aseev; P. Maksyutenko; T. R. Rizzo et al.

Chemical Physics Letters. 2013.

DOI : 10.1016/j.cplett.2013.03.007.

Laser Spectroscopic Study of Cold Host–Guest Complexes of Crown Ethers in the Gas Phase

Y. Inokuchi; R. Kusaka; T. Ebata; O. V. Boyarkin; T. R. Rizzo

ChemPhysChem. 2013.

DOI : 10.1002/cphc.201200746.

Assessing the performance of computational methods for the prediction of the ground state structure of a cyclic decapeptide

M. Doemer; M. Guglielmi; P. Athri; N. S. Nagornova; T. R. Rizzo et al.

International Journal of Quantum Chemistry. 2013.

DOI : 10.1002/qua.24085.

2012

Linear and Time-Resolved THz Spectroscopy of Photonic and Charge Transporting Systems

J. C. Brauer / J. E. Moser (Dir.)

Lausanne, EPFL, 2012.

DOI : 10.5075/epfl-thesis-5444.

Stark coefficients for highly excited rovibrational states of H2O

M. Grechko; O. Aseev; T. R. Rizzo; N. F. Zobov; L. Lodi et al.

Journal of Chemical Physics. 2012.

DOI : 10.1063/1.4730295.

Global spectroscopy of the water monomer

O. Polyansky; N. Zobov; I. Mizus; L. Lodi; S. Yurchenko et al.

Philosophical Transactions of the Royal Society of London Series a Mathematical and Physical Sciences. 2012.

DOI : 10.1098/rsta.2011.0259.

State-resolved spectroscopy of high vibrational levels of water up to the dissociative continuum

P. Maksyutenko; M. Grechko; T. R. Rizzo; O. V. Boyarkin

Philosophical Transactions of the Royal Society of London Series A: Mathematical and Physical Sciences. 2012.

DOI : 10.1098/rsta.2011.0277.

Interplay of Intra- and Intermolecular H-Bonding in a Progressively Solvated Macrocyclic Peptide

N. S. Nagornova; T. R. Rizzo; O. V. Boyarkin

Science. 2012.

DOI : 10.1126/science.1218709.

Ion Selectivity of Crown Ethers Investigated by UV and IR Spectroscopy in a Cold Ion Trap

Y. Inokuchi; O. V. Boyarkin; R. Kusaka; T. Haino; T. Ebata et al.

Journal of Physical Chemistry A. 2012.

DOI : 10.1021/jp3011519.

Conformational distribution of bradykinin [bk+2H]2+ revealed by cold ion spectroscopy coupled with FAIMS

G. Papadopoulos; A. Svendsen; O. V. Boyarkin; T. R. Rizzo

Journal of the American Society for Mass Spectrometry. 2012.

DOI : 10.1007/s13361-012-0384-0.

UV and IR spectroscopy of cold 1,2-dimethoxybenzene complexes with alkali metal ions

Y. Inokuchi; O. V. Boyarkin; T. Ebata; T. R. Rizzo

Physical Chemistry Chemical Physics. 2012.

DOI : 10.1039/C2CP24018A.

Conformation-Specific Spectroscopy of Peptide Fragment Ions in a low-Temperature Ion Trap

T. N. Wassermann; O. Boyarkine; B. Paizs; T. R. Rizzo

JASMS. 2012.

DOI : 10.1007/s13361-012-0368-0.

2011

Conformation-specific infrared spectroscopy of gas phase peptides in a cold ion trap

T. R. Rizzo; O. V. Boyarkin; J. A. Stearns; N. Nagornova; C. Seaiby et al.

2011. 241st National Meeting and Exposition of the American-Chemical-Society (ACS) , Anaheim, CA , Mar 27-31, 2011. p. -.

Cold Ion Spectroscopy of Biological Molecules in the Gas Phase

N. Nagornova / O. Boyarkine (Dir.)

Lausanne, EPFL, 2011.

DOI : 10.5075/epfl-thesis-5252.

Cold Ion Spectroscopy Reveals the Intrinsic Structure of a Decapeptide

N. S. Nagornova; M. Guglielmi; M. Doemer; I. Tavernelli; U. Rothlisberger et al.

Angewandte Chemie, International Edition. 2011.

DOI : 10.1002/anie.201100702.

Spectroscopy of mobility-selected biomolecular ions

G. Papadopoulos; A. Svendsen; O. V. Boyarkin; T. R. Rizzo

Faraday Discussions. 2011.

DOI : 10.1039/C0FD00004C.

UV Spectroscopic Studies of Cold Alkali Metal Ion–Crown Ether Complexes in the Gas Phase

Y. Inokuchi; O. V. Boyarkin; R. Kusaka; T. Haino; T. Ebata et al.

Journal of the American Chemical Society. 2011.

DOI : 10.1021/ja2046205.

2010

Using differential ion mobility as a conformational filter for cold ion spectroscopy

Y. Papadopoulos; A. Svendsen; O. V. Boyarkin; T. R. Rizzo

2010. p. -.

Fragmentation mechanisms of electronically excited peptides in a cold ion trap

M. Guidi; J. A. Stearns; O. V. Boyarkin; T. R. Rizzo

2010. p. -.

Communication: Feshbach resonances in the water molecule revealed by state-selective spectroscopy (vol 133, 081103, 2010)

M. Grechko; P. Maksyutenko; T. R. Rizzo; O. V. Boyarkin

Journal Of Chemical Physics. 2010.

DOI : 10.1063/1.3504864.

Structure and Bonding of Isoleptic Coinage Metal (Cu, Ag, Au) Dimethylaminonitrenes in the Gas Phase

A. Fedorov; E. P. A. Couzijn; N. S. Nagornova; O. V. Boyarkin; T. R. Rizzo et al.

Journal of the American Chemical Society. 2010.

DOI : 10.1021/ja104649k.

Quantitative State-Selective Spectroscopy of Water Below and Above the First Dissociation Limit

M. Grechko / O. Boyarkine (Dir.)

Lausanne, EPFL, 2010.

DOI : 10.5075/epfl-thesis-4843.

Feshbach resonances in the water molecule revealed by state-selective spectroscopy

M. Grechko; P. Maksyutenko; T. R. Rizzo; O. V. Boyarkin

Journal of Chemical Physics. 2010.

DOI : 10.1063/1.3472312.

A new tandem mass spectrometer for photofragment spectroscopy of cold, gas-phase molecular ions

A. Svendsen; U. Lorenz; O. V. Boyarkin; T. R. Rizzo

Review of Scientific Instruments. 2010.

DOI : 10.1063/1.3458014.

Highly-resolved Spectra of Gas-phase Gramicidin S: A Benchmark for Peptide Structure Calculations

N. S. Nagornova; T. R. Rizzo; O. V. Boyarkin

Journal of the American Chemical Society. 2010.

DOI : 10.1021/ja910118j.

2009

State-selective spectroscopy of water up to its first dissociation limit

M. Grechko; O. V. Boyarkin; T. R. Rizzo; P. Maksyutenko; N. F. Zobov et al.

Journal of Chemical Physics. 2009.

DOI : 10.1063/1.3273207.

Spectroscopic studies of cold, gas-phase biomolecular ions

T. R. Rizzo; J. A. Stearns; O. V. Boyarkin

International Reviews in Physical Chemistry. 2009.

DOI : 10.1080/01442350903069931.

Spectroscopy of Protonated Peptides Assisted by Infrared Multiple Photon Excitation

M. Guidi; U. J. Lorenz; G. Papadopoulos; O. V. Boyarkin; T. R. Rizzo

Journal of Physical Chemistry A. 2009.

DOI : 10.1021/jp811243w.

Spectroscopy and Conformational Preferences of Gas-Phase Helices

J. A. Stearns; C. Seaiby; O. V. Boyarkin; T. R. Rizzo

Physical Chemistry Chemical Physics. 2009.

DOI : 10.1039/b814143f.

2008

PHYS 12-Spectroscopic probes of cold, gas-phase biomolecular ions: From amino acids to helical peptides

J. Stearns; M. Guidi; C. Seaiby; O. V. Boyarkin; T. R. Rizzo

2008. 236th National Meeting of the American-Chemical-Society , Philadelphia, PA , Aug 17-21, 2008. p. -.

Collisionally-assisted spectroscopy of water from 27000 to 34000 cm-1

M. Grechko; P. Maksyutenko; T. R. Rizzo; O. V. Boyarkin; N. F. Zobov et al.

Journal of Physical Chemistry A. 2008.

DOI : 10.1021/jp805849q.

Effects of N-terminus substitution on the structure and spectroscopy of gas-phase helices

J. A. Stearns; O. V. Boyarkin; T. R. Rizzo

CHIMIA. 2008.

DOI : 10.2533/chimia.2008.240.

Multiple-resonance spectroscopy of high vibrational levels in water and methanol

P. Maksyutenko / T. Rizzo (Dir.)

Lausanne, EPFL, 2008.

DOI : 10.5075/epfl-thesis-4067.

2007

Spectroscopic signatures of gas-phase helices: Ac-Phe-(Ala)5-Lys-H+ and Ac-Phe-(Ala)10-Lys-H+

J. A. Stearns; O. V. Boyarkin; T. R. Rizzo

Journal of the American Chemical Society. 2007.

DOI : 10.1021/ja076507s.

Conformation-specific infrared and ultraviolet spectroscopy of tyrosine-based protonated dipeptides

J. A. Stearns; M. Guidi; O. V. Boyarkin; T. R. Rizzo

Journal of Chemical Physics. 2007.

DOI : 10.1063/1.2798111.

Conformation-specific spectroscopy and photodissociation of cold, protonated tyrosine and phenylalanine

J. A. Stearns; S. Mercier; C. Seaiby; M. Guidi; O. V. Boyarkin et al.

Journal of the American Chemical Society. 2007.

DOI : 10.1021/ja0736010.

Approaching the full set of energy levels of water

P. Maksyutenko; N. F. Zobov; S. V. Shirin; O. L. Polyansky; J. S. Muenter et al.

Journal of Chemical Physics. 2007.

DOI : 10.1063/1.2748751.

Isotopically selective collisional vibrational energy transfer in CF3H

R. Bossart; O. V. Boyarkin; A. A. Makarov; T. R. Rizzo

Journal of Chemical Physics. 2007.

DOI : 10.1063/1.2433946.

Conformational dependence of intramolecular vibrational redistribution in methanol

P. Maksyutenko; O. V. Boyarkin; T. R. Rizzo; D. S. Perry

Journal of Chemical Physics. 2007.

DOI : 10.1063/1.2431367.

2006

Microsolvation effects on the excited state dynamics of protonated tryptophan

S. R. Mercier; O. V. Boyarkin; A. Kamariotis; M. Guglielmi; I. Tavernelli et al.

Journal of the American Chemical Society. 2006.

DOI : 10.1021/ja065980n.

A direct measurement of the dissociation energy of water

P. Maksyutenko; T. R. Rizzo; O. V. Boyarkin

Journal of Chemical Physics. 2006.

DOI : 10.1063/1.2387163.

Efficient, highly selective laser isotope separation of carbon-13

M. N. Polianski; T. R. Rizzo; O. V. Boyarkin

Applied Physics B-Lasers and Optics. 2006.

DOI : 10.1007/s00340-006-2176-3.

Electronic spectroscopy of cold, protonated tryptophan and tyrosine

O. V. Boyarkin; S. R. Mercier; A. Kamariotis; T. R. Rizzo

Journal of the American Chemical Society. 2006.

DOI : 10.1021/ja058383u.

Infrared spectroscopy of hydrated amino acids in the gas phase: protonated and lithiated valine

A. Kamariotis; O. V. Boyarkin; S. R. Mercier; R. D. Beck; M. F. Bush et al.

Journal of the American Chemical Society. 2006.

DOI : 10.1021/ja056079v.

2005

Vibrational overtone spectroscopy of jet-cooled methanol from 5000 to 14000 cm(-1)

D. Rueda; O. Boyarkin; T. Rizzo; A. Chirokolava; D. Perry

Journal of Chemical Physics. 2005.

DOI : 10.1063/1.1833353.

2004

Collisionally assisted, highly selective laser isotope separation of carbon-13

M. Polianski; O. Boyarkin; T. Rizzo

Journal of Chemical Physics. 2004.

DOI : 10.1063/1.1822918.

2003

Infrared laser chemistry of trichlorosilane in view of silicon isotope separation

M. Polianski; O. Boyarkin; T. Rizzo; V. Apatin; V. Laptev et al.

Journal of Physical Chemistry A. 2003.

DOI : 10.1021/jp0356362.

Collisionally enhanced isotopic selectivity in multiphoton dissociation of vibrationally excited CF3H

O. Boyarkin; M. Kowalczyk; T. Rizzo

JOURNAL OF CHEMICAL PHYSICS. 2003.

DOI : 10.1063/1.1524177.

2002

Nonlinear intensity dependence in the infrared multiphoton excitation and dissociation of methanol pre-excited to different energies

O. Boyarkin; T. Rizzo; D. Rueda; M. Quack; G. Seyfang

JOURNAL OF CHEMICAL PHYSICS. 2002.

DOI : 10.1063/1.1501280.

Isotopically selective infrared multiphoton dissociation of vibrationally excited SiH4

J. Makowe; O. Boyarkin; T. Rizzo

JOURNAL OF PHYSICAL CHEMISTRY A. 2002.

DOI : 10.1021/jp015609g.

Rotational and torsional analysis of the OH-stretch third overtone in (CH3OH)-C-13

A. Chirokolava; D. Perry; O. Boyarkin; M. Schmid; T. Rizzo

JOURNAL OF MOLECULAR SPECTROSCOPY. 2002.

DOI : 10.1006/jmsp.2001.8506.

Torsion-rotation analysis of OH stretch overtone-torsion combination bands in methanol

D. Rueda; O. Boyarkin; T. Rizzo; I. Mukhopadhyay; D. Perry

JOURNAL OF CHEMICAL PHYSICS. 2002.

DOI : 10.1063/1.1421357.

2000

Collision-free infrared multiphoton dissociation of silane

J. Makowe; O. Boyarkin; T. Rizzo

JOURNAL OF PHYSICAL CHEMISTRY A. 2000.

DOI : 10.1021/jp002566f.

Intramolecular energy transfer in highly vibrationally excited methanol. IV. Spectroscopy and dynamics of (CH3OH)-C-13

A. Chirokolava; D. Perry; O. Boyarkin; M. Schmid; T. Rizzo

JOURNAL OF CHEMICAL PHYSICS. 2000.

DOI : 10.1063/1.1323507.

1999

Intramolecular energy transfer in highly vibrationally excited methanol. III. Rotational and torsional analysis

O. Boyarkin; T. Rizzo; D. Perry

JOURNAL OF CHEMICAL PHYSICS. 1999.

Intramolecular energy transfer in highly vibrationally excited methanol. II. Multiple time scales of energy redistribution

O. Boyarkin; T. Rizzo; D. Perry

JOURNAL OF CHEMICAL PHYSICS. 1999.

1998

Highly efficient optically pumped NH3 laser with near diffraction limited output

J. Makowe; O. Boyarkin; T. Rizzo

REVIEW OF SCIENTIFIC INSTRUMENTS. 1998.

DOI : 10.1063/1.1149247.

1997

Intramolecular energy transfer in highly vibrationally excited methanol .1. Ultrafast dynamics

O. Boyarkin; L. Lubich; R. Settle; D. Perry; T. Rizzo

JOURNAL OF CHEMICAL PHYSICS. 1997.

DOI : 10.1063/1.475041.

State-to-state studies of intramolecular dynamics and unimolecular reactions

B. Kuhn; O. Boyarkin; T. Rizzo

BERICHTE DER BUNSEN-GESELLSCHAFT. 1997.

DOI : 10.1002/bbpc.19971010305.

1996

Secondary time scales of intramolecular vibrational energy redistribution in CF3H studied by vibrational overtone spectroscopy

O. Boyarkin; T. Rizzo

JOURNAL OF CHEMICAL PHYSICS. 1996.

DOI : 10.1063/1.472482.

1995

ROTATIONAL STATE-SELECTED VIBRATIONAL OVERTONE SPECTROSCOPY OF JET-COOLED MOLECULES

O. BOYARKIN; T. RIZZO

JOURNAL OF CHEMICAL PHYSICS. 1995.

DOI : 10.1063/1.469723.

VIBRATIONAL OVERTONE SPECTRA OF JET-COOLED CF3H BY INFRARED-LASER ASSISTED PHOTOFRAGMENT SPECTROSCOPY

O. BOYARKIN; R. SETTLE; T. RIZZO

BERICHTE DER BUNSEN-GESELLSCHAFT. 1995.

Multiple timescales in the intramolecular vibrational energy redistribution of highly excited methanol

L. Lubich; O. Boyarkin; R. Settle; D. Perry; T. Rizzo

FARADAY DISCUSSIONS. 1995.